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After a successful interview at an engineering firm, Julio waited by the phone, hoping to hear that he had gotten a summer internship, every call, though, was a twelve-year-old boy requesting to speak to Rosita, Julio's youngest sister.

Every call was a twelve-year-old boy is a main clause. In this sentence, though is an interrupter because it is breaking the flow of that clause. An interrupter needs a comma both in front and behind it.

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